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摘要
摘要
An updated collection of detailed procedures used to degrade and dispose of a broad range of hazardous chemicals whether in bulk quantities, solutions in various solvents or spills. This edition features new chapters on the removal of metal ions and biological stains from solution; the degradation of mycotoxins, enzyme inhibitors, polycyclic heterocyclic hydrocarbons and highly reactive reagents such as butyllithium, peracids and phosgene as well as the use of much less hazardous reagents including molecular sieves. A list of hazardous compounds indexed by name, molecular formula and CAS Registry Number offers ready access to the data.
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This very useful book consists of 43 detailed descriptions of methods of degrading and decontaminating hazardous chemicals ("destruction" is a misleading term) at the laboratory scale. These descriptions are prefaced by a brief but thoughtful and professional discussion of the neutralization methods themselves, and of the additional hazards introduced by the methods and by the reagents used in detoxifying. The number of actual toxic substances discussed is small, but many of the sections apply to whole classes of compounds. The audience addressed is assumed to be professional; this is not a safety handbook for student laboratory assistants. In most cases, the description of a method ends with a phrase like, "Dispose of the product," assuming explicitly that safe and responsible disposal procedures for relatively harmless substances are known to and within the competence of the reader. Analytical methods for confirming substantial removal of the hazardous substance are given in many, but not all, cases. Substances discussed are indexed by molecular formula, by name, and by Chemical Abstracts Service Registry Number. Possibly because both authors are at the National Cancer Institute, relatively exotic mutagens, carcinogens, and antineoplastic agents are rather well represented relative to toxic inorganics like lead or arsenic compounds. This book should be on the reference shelf in every undergraduate and graduate laboratory. -T. R. Blackburn, St. Andrews Presbyterian College
目录
Acid Halides and Anhydrides |
Aflatoxins |
Alkali and Alkaline Earth Metals |
Antineoplastic Alkylating Agents |
Aromatic Amines |
Azides |
Biological Stains |
Boron Trifluoride and Inorganic Fluorides |
Butyllithium |
Calcium Carbide |
Carbamic Acid Esters |
Cisplatin |
Citrinin |
Complex Metal Hydrides |
Cycloserine |
Dimethyl Sulfate and Related Compounds |
Haloethers |
Heavy Metals |
Mercury |
Mitomycin C. Nitrosourea Drugs |
Ochratoxin A. Organic Nitriles |
Patulin |
Peroxides and Hydroperoxides |
Picric Acid |
Protease Inhibitors |
Sodium Amide |
Sulfur-Containing Compounds |
Uranyl Compounds |
Appendices |
Indexes |